Synthesis, Characterization and Magnetic Studies of Cobalt (II), Manganese (II) and Copper (II) Complexes containing Nitrogen-Oxygen Donor Ligands

Zahra, Asmat; Mahmud, Tariq; Shad, Hazoor Ahmad; Tahir, Muhammad Nawaz; Rehman, Hajira; Shahzady, Tanzeela Gulab; Ali, Zufiqar

Asmat Zahra, Tariq Mahmud, Hazoor Ahmad Shad, Muhammad Nawaz Tahir, Hajira Rehman, Tanzeela Gulab Shahzady, Zufiqar Ali

Synthesis, Characterization and Magnetic Studies of Cobalt (II), Manganese (II) and Copper (II) Complexes containing Nitrogen-Oxygen Donor Ligands

Abstract:

Transition metal complexes, [M(COOPh)2(TMEDA)µ(OH2)], (where M=Co+2 and Mn+2) and [Cu3(COOPh)2(TEA)2(CH3COO)2] have been synthesized by using sodium benzoate, tetramethyl-ethylenediamine and triethanolamine. The bonding nature and structure of complexes (1), (2) and (3) were explored through X-ray crystallography, IR, elemental analysis and magnetic studies. Single crystal X-ray analysis showed that in (1) and (2) complexes, each M (II) is bridged by two benzoate ions, one TMEDA and one water molecule while in (3) complex, Cu1 is coordinated by four oxygen atoms, two from TEA and two from carboxylate group while Cu2 is coordinated by three oxygen atoms and one nitrogen atom. All three complexes displayed triclinic system with space group P-1. Vibrating sample magnetometer measurement justified that these complexes are soft magnetic materials and can retain a certain value of magnetization even when magnetic field is removed.

Keywords:
Tetramethylethylenediamine; Triethanolamine; Binuclear complex; Soft magnetic material

Issue: 2018, Volume 69, Issue 7

Pages: 1722-1727

Publication date: 2018/8/15

https://doi.org/10.37358/RC.18.7.6404

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Citation Styles

Cite this article as:
ZAHRA, A., MAHMUD, T., SHAD, H.A., TAHIR, M.N., REHMAN, H., SHAHZADY, T.G., ALI, Z., Synthesis, Characterization and Magnetic Studies of Cobalt (II), Manganese (II) and Copper (II) Complexes containing Nitrogen-Oxygen Donor Ligands, Rev. Chim., 69(7), 2018, 1722-1727.

Vancouver
Zahra A, Mahmud T, Shad HA, Tahir MN, Rehman H, Shahzady TG, Ali Z. Synthesis, Characterization and Magnetic Studies of Cobalt (II), Manganese (II) and Copper (II) Complexes containing Nitrogen-Oxygen Donor Ligands. Rev. Chim.[internet]. 2018 Jul;69(7):1722-1727. Available from: https://doi.org/10.37358/RC.18.7.6404

APA 6th edition
Zahra, A., Mahmud, T., Shad, H.A., Tahir, M.N., Rehman, H., Shahzady, T.G. & Ali, Z. (2018). Synthesis, Characterization and Magnetic Studies of Cobalt (II), Manganese (II) and Copper (II) Complexes containing Nitrogen-Oxygen Donor Ligands. Revista de Chimie, 69(7), 1722-1727. https://doi.org/10.37358/RC.18.7.6404

Harvard
Zahra, A., Mahmud, T., Shad, H.A., Tahir, M.N., Rehman, H., Shahzady, T.G., Ali, Z. (2018). 'Synthesis, Characterization and Magnetic Studies of Cobalt (II), Manganese (II) and Copper (II) Complexes containing Nitrogen-Oxygen Donor Ligands', Revista de Chimie, 69(7), pp. 1722-1727. https://doi.org/10.37358/RC.18.7.6404

IEEE
A. Zahra, T. Mahmud, H.A. Shad, M.N. Tahir, H. Rehman, T.G. Shahzady, Z. Ali, "Synthesis, Characterization and Magnetic Studies of Cobalt (II), Manganese (II) and Copper (II) Complexes containing Nitrogen-Oxygen Donor Ligands". Revista de Chimie, vol. 69, no. 7, pp. 1722-1727, 2018. [online]. https://doi.org/10.37358/RC.18.7.6404

Text
Asmat Zahra, Tariq Mahmud, Hazoor Ahmad Shad, Muhammad Nawaz Tahir, Hajira Rehman, Tanzeela Gulab Shahzady, Zufiqar Ali,
Synthesis, Characterization and Magnetic Studies of Cobalt (II), Manganese (II) and Copper (II) Complexes containing Nitrogen-Oxygen Donor Ligands,
Revista de Chimie,
Volume 69, Issue 7,
2018,
Pages 1722-1727,
ISSN 2668-8212,
https://doi.org/10.37358/RC.18.7.6404.
(https://revistadechimie.ro/Articles.asp?ID=6404)
Keywords: Tetramethylethylenediamine; Triethanolamine; Binuclear complex; Soft magnetic material

RIS
TY - JOUR
T1 - Synthesis, Characterization and Magnetic Studies of Cobalt (II), Manganese (II) and Copper (II) Complexes containing Nitrogen-Oxygen Donor Ligands
A1 - Zahra, Asmat
A2 - Mahmud, Tariq
A3 - Shad, Hazoor Ahmad
A4 - Tahir, Muhammad Nawaz
A5 - Rehman, Hajira
A6 - Shahzady, Tanzeela Gulab
A7 - Ali, Zufiqar
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2018
VL - 69
IS - 7
SP - 1722
EP - 1727
UR - https://doi.org/10.37358/RC.18.7.6404
KW - Tetramethylethylenediamine; Triethanolamine; Binuclear complex; Soft magnetic material
ER -

BibTex
@article{RevCh2018P1722,
author = {Zahra Asmat and Mahmud Tariq and Shad Hazoor Ahmad and Tahir Muhammad Nawaz and Rehman Hajira and Shahzady Tanzeela Gulab and Ali Zufiqar},
title = {Synthesis, Characterization and Magnetic Studies of Cobalt (II), Manganese (II) and Copper (II) Complexes containing Nitrogen-Oxygen Donor Ligands},
journal = {Revista de Chimie},
volume = {69},
number = {7},
pages = {1722-1727},
year = {2018},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.18.7.6404},
url = {https://revistadechimie.ro/Articles.asp?ID=6404}
}

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