Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes

Tabassam, Misbah; Imran, Muhammad; Farooq, Amna; Gillani, Syeda Robina; Mehmood, Zaid; Gulzar, Asad; Mitu, Liviu

Misbah Tabassam, Muhammad Imran, Amna Farooq, Syeda Robina Gillani, Zaid Mehmood, Asad Gulzar, Liviu Mitu

Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes

Abstract:

In this paper we report the preparation of two (h3-allyl)carbonylnitrosyltriphenylphosphine iron complexes i.e.(p-allyl)carbonylnitrosyltriphenylphosphine iron (1) and (2-methyl-p-allyl) carbonylnit rosyltriphenylphosphine iron (2). These complexes (1) and (2) were prepared by reacting (p-allyl)dicarbonylnitrosyl iron and (2-methyl-p-allyl)dicarbonylnitrosyl iron with triphenylphosphine under inert atmospheric conditions. Both the resulting complexes were sufficiently and well characterized by IR, 1H NMR, 13C NMR, ESI/MS, HRMS and single crystal XRD. Triphenylphosphine ligand was found to be strong sigma donor and replaced carbonyl ligand readily. XRD revealed that the geometry of iron in both complexes is distorted octahedral.

Keywords:
Iron; triphenylphosphine; allyl complexes

Issue: 2019, Volume 70, Issue 11

Pages: 3893-3898

Publication date: 2019/12/15

https://doi.org/10.37358/RC.70.19.11.7666

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This article is published under the Creative Commons Attribution 4.0 International License

Citation Styles

Cite this article as:
TABASSAM, M., IMRAN, M., FAROOQ, A., GILLANI, S.R., MEHMOOD, Z., GULZAR, A., MITU, L., Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes, Rev. Chim., 70(11), 2019, 3893-3898.

Vancouver
Tabassam M, Imran M, Farooq A, Gillani SR, Mehmood Z, Gulzar A, Mitu L. Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes. Rev. Chim.[internet]. 2019 Nov;70(11):3893-3898. Available from: https://doi.org/10.37358/RC.70.19.11.7666

APA 6th edition
Tabassam, M., Imran, M., Farooq, A., Gillani, S.R., Mehmood, Z., Gulzar, A. & Mitu, L. (2019). Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes. Revista de Chimie, 70(11), 3893-3898. https://doi.org/10.37358/RC.70.19.11.7666

Harvard
Tabassam, M., Imran, M., Farooq, A., Gillani, S.R., Mehmood, Z., Gulzar, A., Mitu, L. (2019). 'Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes', Revista de Chimie, 70(11), pp. 3893-3898. https://doi.org/10.37358/RC.70.19.11.7666

IEEE
M. Tabassam, M. Imran, A. Farooq, S.R. Gillani, Z. Mehmood, A. Gulzar, L. Mitu, "Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes". Revista de Chimie, vol. 70, no. 11, pp. 3893-3898, 2019. [online]. https://doi.org/10.37358/RC.70.19.11.7666

Text
Misbah Tabassam, Muhammad Imran, Amna Farooq, Syeda Robina Gillani, Zaid Mehmood, Asad Gulzar, Liviu Mitu,
Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes,
Revista de Chimie,
Volume 70, Issue 11,
2019,
Pages 3893-3898,
ISSN 2668-8212,
https://doi.org/10.37358/RC.70.19.11.7666.
(https://revistadechimie.ro/Articles.asp?ID=7666)
Keywords: Iron; triphenylphosphine; allyl complexes

RIS
TY - JOUR
T1 - Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes
A1 - Tabassam, Misbah
A2 - Imran, Muhammad
A3 - Farooq, Amna
A4 - Gillani, Syeda Robina
A5 - Mehmood, Zaid
A6 - Gulzar, Asad
A7 - Mitu, Liviu
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2019
VL - 70
IS - 11
SP - 3893
EP - 3898
UR - https://doi.org/10.37358/RC.70.19.11.7666
KW - Iron
KW - triphenylphosphine
KW - allyl complexes
ER -

BibTex
@article{RevCh2019P3893,
author = {Tabassam Misbah and Imran Muhammad and Farooq Amna and Gillani Syeda Robina and Mehmood Zaid and Gulzar Asad and Mitu Liviu},
title = {Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes},
journal = {Revista de Chimie},
volume = {70},
number = {11},
pages = {3893-3898},
year = {2019},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.70.19.11.7666},
url = {https://revistadechimie.ro/Articles.asp?ID=7666}
}

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