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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2019, Volume 70, Issue 5, 1707-1711

https://doi.org/10.37358/RC.19.5.7198

Gheorghe Surpateanu, Ileana Denisa Nistor, Ana-Maria Georgescu, Neculai Catalin Lungu

Syntone Chemistry. Theoretical study on the formation of glycine, alannine and serine

Abstract:

Three synthons: methylene, nitrene and carbon monoxide form aziridinone in the presence of molecular nitrogen at low temperatures. This one, in contact with the same three synthons could form the precursors of the first proteinogenic amino acids. This paper is a theoretical, thermodynamically and reactivity study concerning the formation of the three previously named amino acids at low temperature conditions. The key intermediates are identified in the formation of the three amino acids: aziridinone, aziridinonil and methyl-aziridinonil radicals. The quantitative results, enthalpies of formation, reaction enthalpies and free energies were taken from quantum mechanical calculations acquired by density functional method (DFT): B88-LYP.
Keywords:
methylene; nitrene; carbon monoxide; aziridinone; methylaziridinone

Issue: 2019, Volume 70, Issue 5
Pages: 1707-1711
Publication date: 2019/6/15
https://doi.org/10.37358/RC.19.5.7198
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Creative Commons License
This article is published under the Creative Commons Attribution 4.0 International License
Citation Styles
Cite this article as:
SURPATEANU, G., NISTOR, I.D., GEORGESCU, A., LUNGU, N.C., Syntone Chemistry. Theoretical study on the formation of glycine, alannine and serine, Rev. Chim., 70(5), 2019, 1707-1711.

Vancouver
Surpateanu G, Nistor ID, Georgescu A, Lungu NC. Syntone Chemistry. Theoretical study on the formation of glycine, alannine and serine. Rev. Chim.[internet]. 2019 May;70(5):1707-1711. Available from: https://doi.org/10.37358/RC.19.5.7198


APA 6th edition
Surpateanu, G., Nistor, I.D., Georgescu, A. & Lungu, N.C. (2019). Syntone Chemistry. Theoretical study on the formation of glycine, alannine and serine. Revista de Chimie, 70(5), 1707-1711. https://doi.org/10.37358/RC.19.5.7198


Harvard
Surpateanu, G., Nistor, I.D., Georgescu, A., Lungu, N.C. (2019). 'Syntone Chemistry. Theoretical study on the formation of glycine, alannine and serine', Revista de Chimie, 70(5), pp. 1707-1711. https://doi.org/10.37358/RC.19.5.7198


IEEE
G. Surpateanu, I.D. Nistor, A. Georgescu, N.C. Lungu, "Syntone Chemistry. Theoretical study on the formation of glycine, alannine and serine". Revista de Chimie, vol. 70, no. 5, pp. 1707-1711, 2019. [online]. https://doi.org/10.37358/RC.19.5.7198


Text
Gheorghe Surpateanu, Ileana Denisa Nistor, Ana-Maria Georgescu, Neculai Catalin Lungu,
Syntone Chemistry. Theoretical study on the formation of glycine, alannine and serine,
Revista de Chimie,
Volume 70, Issue 5,
2019,
Pages 1707-1711,
ISSN 2668-8212,
https://doi.org/10.37358/RC.19.5.7198.
(https://revistadechimie.ro/Articles.asp?ID=7198)
Keywords: methylene; nitrene; carbon monoxide; aziridinone; methylaziridinone


RIS
TY - JOUR
T1 - Syntone Chemistry. Theoretical study on the formation of glycine, alannine and serine
A1 - Surpateanu, Gheorghe
A2 - Nistor, Ileana Denisa
A3 - Georgescu, Ana-Maria
A4 - Lungu, Neculai Catalin
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2019
VL - 70
IS - 5
SP - 1707
EP - 1711
UR - https://doi.org/10.37358/RC.19.5.7198
KW - methylene
KW - nitrene
KW - carbon monoxide
KW - aziridinone
KW - methylaziridinone
ER -


BibTex
@article{RevCh2019P1707,
author = {Surpateanu Gheorghe and Nistor Ileana Denisa and Georgescu Ana-Maria and Lungu Neculai Catalin},
title = {Syntone Chemistry. Theoretical study on the formation of glycine, alannine and serine},
journal = {Revista de Chimie},
volume = {70},
number = {5},
pages = {1707-1711},
year = {2019},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.19.5.7198},
url = {https://revistadechimie.ro/Articles.asp?ID=7198}
}
 
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