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REVISTA DE CHIMIE
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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2006, Volume 57, Issue 5,





Optimized Digestion Method for Blood Sample Followed
by Mercury Determination by Atomic Absorption Spectometry at 184,9 nm


Abstract:

A complex method was proposed and optimized for blood samples’ digestion to make possible the determination of total mercury by using cold vapor atomic absorption spectrometry detection (CVAAS), at the main resonance line of mercury (184.9 nm). A new type of a non dispersive mercury minianalyzer developed by University of Bucharest was used based on the measurement of the absorption of mercury line at 184.9 nm. For validating the developed method, this new instrument was coupled with a conventional atomic absorption spectrometer, the measurements being performed simultaneously at two different wavelengths: 184.9 nm and 253.7 nm. To check the whole method, a standard addition method was applied and the recoveries of mercury spiked to each blood analysed sample were ]90%. The results showed a better sensitivity using the mercury absorption line at 184.9 nm compared with the sensitivity obtained by conventional CVAAS at 253.7 nm line. The method was successfully applied in routine analysis for determination of mercury in blood samples. Keywords: mercury determination, mercury in blood sample, blood sample digestion, cold vapor atomic absorption spectrometry at 184,9 nm

Issue: 2006, Volume 57, Issue 5
Pages:
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