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Revista de Chimie (Rev. Chim.), Year 2007, Volume 58, Issue 8,





A New Class of Organo-Inorganic Layered Perovskites
with Potential Applications in Optoelectronics

Abstract:

Recently, much attention has been devoted to organo-inorganic hybrid materials due to the tuneability of their structural features and interesting physical properties, especially their use as potential materials for optoelectronic devices. This paper presents the characterization of new crystalline composites of the layered perovskite type obtained in the systems of divalent (Cu, Sn, Pb, Fe) metallic halides and ammonium quaternary salts of amino alcohols ([HO-(CH2)n-N(CH3)3]+). The layer perovskites of chol2[CuxM1-xCl4] and chol2[FexPb1-xCl4] type (where M = Sn, Pb; x = 0.00; 0.25; 0.50 and chol = [HO-(CH2)2-N(CH3)3]+) have been synthesized and characterized by electronic and IR spectra, thermal analysis, X-ray diffraction pattern as well as electrical properties. Keywords: layered perovskite, quaternary ammonium salt, aminoalchols, optoelectronics


Issue: 2007, Volume 58, Issue 8
Pages:
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