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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2008, Volume 59, Issue 7,

https://doi.org/10.37358/RC.08.7.1888

Maria Maganu, Filip Chiraleu, Constantin Draghici, Gheorghe Mihai

Asymetrical Dimer - allyl-palladiu Complexes II. Data from Infrared Spectra and Chemical Behaviour

Abstract:

The previous data obtained by 1H-NMR spectroscopy established the existence of an asymmetry of the bond between Pd and p-allylic groups, even in the p-allyl-Pd complexes dimers which are considered usually symmetric dimers. The asymmetry of the bond depends by the substitutes of the allylic group. Other analytical methods were investigated for additional proof of the obtained results. Thus, this paper discusses how this asymmetry would be reflected in the infrared spectra and in the reaction of the complexes with carbon monoxide.

Keywords:
p-allyl paladium complexes; infrared spectra; asymetrical dimer

Issue: 2008, Volume 59, Issue 7
Pages:
Publication date: 2008/8/9
https://doi.org/10.37358/RC.08.7.1888
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