A Dinuclear Adduct of bis(di-sec-butyl dithiophosphato) Cadmium(II) Built around the Hexamethylenetetramine Cage as Coordination Center

Bolundut, Liviu; Haiduc, Ionel; Mahon, Mary F.; Molloy, Kieran C.

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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2008, Volume 59, Issue 11,

https://doi.org/10.37358/RC.08.11.1998

Liviu Bolundut, Ionel Haiduc, Mary F. Mahon, Kieran C. Molloy

A Dinuclear Adduct of bis(di-sec-butyl dithiophosphato) Cadmium(II) Built around the Hexamethylenetetramine Cage as Coordination Center

Abstract:

Bis(di-sec-butyldithiophosphato)cadmium(II) forms a 2:1 adduct with hexamethylenetetramine (urotropine), which was characterized by FT-IR and NMR spectroscopy. The compound is a dinuclear complex with the cadmium atoms coordinated at two nitrogen atoms of hexamethylenetetramine cage which is the actual coordination center. The X-ray diffraction analysis of the complex reveals a distorted square pyramidal coordination of the five-coordinate cadmium atoms. At each cadmium, one dithiophosphato group behaves as slightly anisobidentate whereas the other one is an isobidentate chelating ligand.

Keywords:
Crystal structure; dinuclear complex; hexamethylenetetramine; coordination center

Issue: 2008, Volume 59, Issue 11

Pages:

Publication date: 2008/10/9

https://doi.org/10.37358/RC.08.11.1998

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This article is published under the Creative Commons Attribution 4.0 International License

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Liviu Bolundut, Ionel Haiduc, Mary F. Mahon, Kieran C. Molloy A Dinuclear Adduct of bis(di-sec-butyl dithiophosphato) Cadmium(II) Built around the Hexamethylenetetramine Cage as Coordination Center

Liviu Bolundut, Ionel Haiduc, Mary F. Mahon, Kieran C. Molloy

A Dinuclear Adduct of bis(di-sec-butyl dithiophosphato) Cadmium(II) Built around the Hexamethylenetetramine Cage as Coordination Center