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https://doi.org/10.37358/Rev.Chim.1949

OSIM Nr. R102355
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Revista de Chimie (Rev. Chim.), Year 2010, Volume 61, Issue 5,





CONSTANTIN MARIN, ALIN TUDORACHE, LUMINIŢA VLĂDESCU
Aluminium Determination and Speciation Modelling in Groundwater from the Area of a Future Radioactive Waste Repository

Abstract:

A study of aluminium concentration distributions in natural groundwater has been conducted, by considering samples collected from the area located in the neighbourhood of Saligny village (Cernavodă -Romania). A GF-AAS method has been developed, tested and used for aluminium content determination. Based on the complete analysis results of the considered groundwater samples, the distribution of the aluminium inorganic species in groundwater has been evaluated. In order to determine the aluminium speciation in the analyzed waters, besides the chemical species included in the PHREEQC code databases, also other ionic associations that aluminium formed with Si species, SO42- , F-, Na+ and K+ ions were considered. The distribution of the water saturation index values calculated on this basis suggests that some mineral species of the red clay layers tend to render soluble when the groundwater is mixed with the surface water. Key words: aluminium, determination, speciation, groundwater, saturation index


Issue: 2010, Volume 61, Issue 5
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