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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie, Volume 62, Issue 1, pp. (2011)


Danut-Gabriel Cozma, Aurel Pui, Remy Ricoux, Jean-Pierre Mahy

Estimation of Kinetic Parameters for the Catalytic Oxidation of Substituted Phenols in Liquid-phase

Abstract:

The cobalt(II) Schiff bases complexes were used as catalysts in an oxidation reaction of substituted phenol with molecular oxygen. The kinetics parameters (reaction order, rate constants) were calculated from the van’t Hoff relation and their variation limits have been subsequently statistically estimated. The dependence of the oxidation reaction rate is evaluated according to the nature of the Schiff base used as a catalyst, using statistical and probabilistic methods.
Keywords:
kinetic parameters; statistical methods; oxidation reactions

Issue: 2011 Volume 62, Number 1
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