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REVISTA DE CHIMIE
Cite as: Rev. Chim.
https://doi.org/10.37358/Rev.Chim.1949

OSIM Nr. R102355
ISSN Online 2668-8212
ISSN Print: 1582-9049
ISSN-L: 1582-9049

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Revista de Chimie (Rev. Chim.), Year 2012, Volume 63, Issue 9,





IRINA GEORGESCU, MIHAELA MURESEANU, GABRIELA CARJA, ION BALASANIAN
Hystidine-Salicylaldehyde Schiff Base Cu(II) Complexes
Immobilized on Mesoporous Materials as Potentially
Biomimetic Oxidation Catalyst

Abstract:

New potentially oxidation catalysts were synthesized by immobilization of Cu(II) biomimetic complex onto amino-functionalized mesoporous SBA-15 silica supports. The copper complex with Schiff bases derived from hystidine and salicylaldehyde, was tethered onto the pores of a NH2-functionalized silica. Characterization by XRD analysis, N2 adsorption-desorption, SEM microscopy, IR and UV-Vis spectroscopy TGA-DTA and elemental analysis confirm the structural integrity of the mesoporous hosts and successful anchoring of the metal complex over the tested support. Catalytic activities of the host free and immobilized complex were tested by oxidation with air of 2,2’ -azino-bis(3-ethylbenzothiazoline-6-sulfonic acid. The activity of the supported metals complex was compared with that of Trametes versicolor laccase, immobilized by the same support. Keywords: SBA-15, Cu (II) complexes, Schiff bases, laccase, biomimetic catalysts

Issue: 2012, Volume 63, Issue 9
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