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REVISTA DE CHIMIE
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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2013, Volume 64, Issue 11,





LIVIU BIRZAN*, VICTORITA TECUCEANU, CRISTIAN ENACHE, ALEXANDRU C. RAZUS
Molecular Ions Resulted in Mass Spectrometer for
1,3-bis(phenylselanyl)-azulenes and Their Oxidized Products

Abstract:

The reported results in this paper confirm the previous statement on the limited validity of the EE rule for the molecular ion generation when ESI method was used in mass spectrometer. Thus, the ratio [M].+/[M+1]+ increases with the molecule oxidizability until the absence of the protonated form; therefore, in several cases the base peak fragment is not always an EE fragment. In addition to the basic fragmentation of the compounds with one selenium atom in the molecule, the presence of the second such atom, especially in higher oxidation states, complicates the splitting in the mass spectrometer. Key words: azulene, selenium compounds, mass spectra, isotopes

Issue: 2013, Volume 64, Issue 11
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