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REVISTA DE CHIMIE
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https://doi.org/10.37358/Rev.Chim.1949

OSIM Nr. R102355
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Revista de Chimie (Rev. Chim.), Year 2015, Volume 66, Issue 7,





MARIAN CRUDU,DOINA SIBIESCU, DANA GURAU,RODICA ROXANA CONSTANTINESCU,ANA MARIA VASILESCU
New Coordination Compounds of Fe(III) with Ligand from N-hydroxysuccinimide with
Applications in Ecologic Leather Tanning Technologies

Abstract:

This paper presents the synthesis and study of three new complexes of iron (III) resulting from the interaction of FeCl3 with N-hydroxysuccinimide in central atom: ligand ratio of 1:1, 1:2 and 1:3. For the study of the new compounds, specific methods for characterisation of complex combinations in solid state were used (derivatography, IR spectroscopy, Mossbauer spectroscopy, X-ray diffraction).The compounds thus obtained (central atom in octahedral arrangement, with high spin and triclinic crystal system) were tested, yielding good results in leather processing technologies, with the aim of totally or partially replacing chromium salts in the tanning operation. Keywords: Fe(III) complexes, n-hydroxysuccinimide ligand, ecologic tanning, IR and Mossbauer spectroscopy, X-ray diffraction

Issue: 2015, Volume 66, Issue 7
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