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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2015, Volume 66, Issue 9,





ALINA-GIORGIANA NEGRU, CECILIA ARSENE, ANA-MARIA ZBANCIOC, IONEL I. MANGALAGIU, ROMEO IULIAN OLARIU
Physico-chemical Behaviour of Newly Synthesized
Macrocyclic Compounds A reality between expectations and experimental evidences

Abstract:

Three newly synthesized macrocyclic amidic compounds have been tested for their potential to act as chelators for various metals. Spectroscopic (Fourier-Transformed-Infrared-Spectroscopy, fluorescence, UV-Vis absorption) and electrometric (conductometry) techniques have been used to characterize the chelating potential of the newly synthesized macrocyclic compounds towards metals such as Ag, Al, Ca, Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Mg, Mn(II), Ni(II), Pb(II) and Zn. Experimental investigations have been undertaken at M:L or L:M ratios of 1:1, 1:2, 1:3 and 1:4. From the interest potential chelators only for one macrocyclic amidic compound some experimental evidences have been obtained for its possible implication in silver ions chelatization both in methanol (MeOH) and methanol-dimethyl sulphoxide (MeOH-DMSO) binary systems. Keywords: macrocyclic amidic compounds, chemosensors, silver ions, chelators


Issue: 2015, Volume 66, Issue 9
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