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REVISTA DE CHIMIE
Cite as: Rev. Chim.
https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2015, Volume 66, Issue 11,





ANA MARIA BARGAN (MATEIUC), GABRIELA CIOBANU, TEODOR MALUTAN, CONSTANTIN LUCA
Influence of Cerium(IV) and Bismuth(III) on the Luminescence Properties of the Nanocrystalline Hydroxyapatite

Abstract:

Cerium(IV)- and bismuth(III)-substituted hydroxyapatite nanoparticles were synthesized by the co-precipitation method from aqueous solutions of various Ce/(Ce+Ca) = XCe or Bi/(Bi+Ca) = XBi atomic ratios ranging from 0 to 0.5. Samples were characterised by scanning electron microscopy (SEM) coupled with X-ray analysis (EDX), X-ray powder diffraction (XRD) and fluorescence spectroscopy. The luminescence characteristics of the Ce4+ and Bi3+ ions in the hydroxyapatite lattice have been studied under the ëexc = 300 nm. The results obtained from the fluorescence spectra revealed that the optical properties of the hydroxyapatite samples are modified by the substitution with cerium or bismuth ions. Keywords: hydroxyapatite, cerium, bismuth, optical properties, luminescence

Issue: 2015, Volume 66, Issue 11
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