Mesoionic 4-(2-Dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates

Chirita, Paul; Asaftei, Iuliean Vasile; Sandu, Ion; Sarbu, Laura Gabriela; Lupu, Vasile Valeriu

Paul Chirita, Iuliean Vasile Asaftei, Ion Sandu, Laura Gabriela Sarbu, Vasile Valeriu Lupu

Mesoionic 4-(2-Dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates

Abstract:

New mesoionic 4-(2-dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates have been obtained from the corresponding 1,3-dithiolium salts under weak basic conditions. The 1,3-dithiolium salts have been synthesized by the cyclocondensation of 1-(4-hydroxyphenyl)-1-oxaethan-2-yl dithiocarbamates. The latter compounds have been obtained from the reaction of the 2-bromo-1-(4-hydroxyphenyl)ethan-1-one with various salts of dithiocarbamic acids. UV-Vis investigations proved the intramolecular charge transfer for the mesoionic 1,3-dithiolium phenolates.

Keywords:
hydroxyacetophenones; dithiocarbamates; 1;3-dithiolium salts; mesoionic compounds; UV-Vis spectroscopy

Issue: 2017, Volume 68, Issue 1

Pages: 147-150

Publication date: 2017/2/15

https://doi.org/10.37358/RC.17.1.5408

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This article is published under the Creative Commons Attribution 4.0 International License

Citation Styles

Cite this article as:
CHIRITA, P., ASAFTEI, I.V., SANDU, I., SARBU, L.G., LUPU, V.V., Mesoionic 4-(2-Dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates, Rev. Chim., 68(1), 2017, 147-150.

Vancouver
Chirita P, Asaftei IV, Sandu I, Sarbu LG, Lupu VV. Mesoionic 4-(2-Dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates. Rev. Chim.[internet]. 2017 Jan;68(1):147-150. Available from: https://doi.org/10.37358/RC.17.1.5408

APA 6th edition
Chirita, P., Asaftei, I.V., Sandu, I., Sarbu, L.G. & Lupu, V.V. (2017). Mesoionic 4-(2-Dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates. Revista de Chimie, 68(1), 147-150. https://doi.org/10.37358/RC.17.1.5408

Harvard
Chirita, P., Asaftei, I.V., Sandu, I., Sarbu, L.G., Lupu, V.V. (2017). 'Mesoionic 4-(2-Dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates', Revista de Chimie, 68(1), pp. 147-150. https://doi.org/10.37358/RC.17.1.5408

IEEE
P. Chirita, I.V. Asaftei, I. Sandu, L.G. Sarbu, V.V. Lupu, "Mesoionic 4-(2-Dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates". Revista de Chimie, vol. 68, no. 1, pp. 147-150, 2017. [online]. https://doi.org/10.37358/RC.17.1.5408

Text
Paul Chirita, Iuliean Vasile Asaftei, Ion Sandu, Laura Gabriela Sarbu, Vasile Valeriu Lupu,
Mesoionic 4-(2-Dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates,
Revista de Chimie,
Volume 68, Issue 1,
2017,
Pages 147-150,
ISSN 2668-8212,
https://doi.org/10.37358/RC.17.1.5408.
(https://revistadechimie.ro/Articles.asp?ID=5408)
Keywords: hydroxyacetophenones; dithiocarbamates; 1;3-dithiolium salts; mesoionic compounds; UV-Vis spectroscopy

RIS
TY - JOUR
T1 - Mesoionic 4-(2-Dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates
A1 - Chirita, Paul
A2 - Asaftei, Iuliean Vasile
A3 - Sandu, Ion
A4 - Sarbu, Laura Gabriela
A5 - Lupu, Vasile Valeriu
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2017
VL - 68
IS - 1
SP - 147
EP - 150
UR - https://doi.org/10.37358/RC.17.1.5408
KW - hydroxyacetophenones
KW - dithiocarbamates
KW - 1
KW - 3-dithiolium salts
KW - mesoionic compounds
KW - UV-Vis spectroscopy
ER -

BibTex
@article{RevCh2017P147,
author = {Chirita Paul and Asaftei Iuliean Vasile and Sandu Ion and Sarbu Laura Gabriela and Lupu Vasile Valeriu},
title = {Mesoionic 4-(2-Dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates},
journal = {Revista de Chimie},
volume = {68},
number = {1},
pages = {147-150},
year = {2017},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.17.1.5408},
url = {https://revistadechimie.ro/Articles.asp?ID=5408}
}

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