NPK Analysis of the Thermal Degradation of Decabromodiphenylether

Dumitras, Mihai; Maftei, Dan; Airinei, Anton; Tudorachi, Nita; Dirtu, Alin Constantin

Mihai Dumitras, Dan Maftei, Anton Airinei, Nita Tudorachi, Alin Constantin Dirtu

NPK Analysis of the Thermal Degradation of Decabromodiphenylether

Abstract:

This study aims to investigate the thermal degradation behavior of decabromodiphenyl ether (BDE 209) by simultaneous TG/DTA under various conditions. Due to low volatility, high elution temperatures are needed when applying chromatographic techniques for this class of flame retardants (FR), resulting in thermal degradation affecting analysis results, but no systematic study has been reported. Kinetic analysis was performed by the non-parametric (NPK) method, and in correlation with evolved gas analysis (EGA) information and molecular modeling results, provided valuable insight into the kinetics and mechanism of BDE 209 thermal degradation. The conclusions were aimed at designing proper specific GC analytical methods for the selected FRs and serving for a better estimation of the human exposure to such compounds.

Keywords:
brominated flame retardants; thermal degradation; TG-DTA; nonparametric kinetics

Issue: 2017, Volume 68, Issue 11

Pages: 2734-2738

Publication date: 2017/12/15

https://doi.org/10.37358/RC.17.11.5965

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This article is published under the Creative Commons Attribution 4.0 International License

Citation Styles

Cite this article as:
DUMITRAS, M., MAFTEI, D., AIRINEI, A., TUDORACHI, N., DIRTU, A.C., NPK Analysis of the Thermal Degradation of Decabromodiphenylether, Rev. Chim., 68(11), 2017, 2734-2738.

Vancouver
Dumitras M, Maftei D, Airinei A, Tudorachi N, Dirtu AC. NPK Analysis of the Thermal Degradation of Decabromodiphenylether. Rev. Chim.[internet]. 2017 Nov;68(11):2734-2738. Available from: https://doi.org/10.37358/RC.17.11.5965

APA 6th edition
Dumitras, M., Maftei, D., Airinei, A., Tudorachi, N. & Dirtu, A.C. (2017). NPK Analysis of the Thermal Degradation of Decabromodiphenylether. Revista de Chimie, 68(11), 2734-2738. https://doi.org/10.37358/RC.17.11.5965

Harvard
Dumitras, M., Maftei, D., Airinei, A., Tudorachi, N., Dirtu, A.C. (2017). 'NPK Analysis of the Thermal Degradation of Decabromodiphenylether', Revista de Chimie, 68(11), pp. 2734-2738. https://doi.org/10.37358/RC.17.11.5965

IEEE
M. Dumitras, D. Maftei, A. Airinei, N. Tudorachi, A.C. Dirtu, "NPK Analysis of the Thermal Degradation of Decabromodiphenylether". Revista de Chimie, vol. 68, no. 11, pp. 2734-2738, 2017. [online]. https://doi.org/10.37358/RC.17.11.5965

Text
Mihai Dumitras, Dan Maftei, Anton Airinei, Nita Tudorachi, Alin Constantin Dirtu,
NPK Analysis of the Thermal Degradation of Decabromodiphenylether,
Revista de Chimie,
Volume 68, Issue 11,
2017,
Pages 2734-2738,
ISSN 2668-8212,
https://doi.org/10.37358/RC.17.11.5965.
(https://revistadechimie.ro/Articles.asp?ID=5965)
Keywords: brominated flame retardants; thermal degradation; TG-DTA; nonparametric kinetics

RIS
TY - JOUR
T1 - NPK Analysis of the Thermal Degradation of Decabromodiphenylether
A1 - Dumitras, Mihai
A2 - Maftei, Dan
A3 - Airinei, Anton
A4 - Tudorachi, Nita
A5 - Dirtu, Alin Constantin
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2017
VL - 68
IS - 11
SP - 2734
EP - 2738
UR - https://doi.org/10.37358/RC.17.11.5965
KW - brominated flame retardants
KW - thermal degradation
KW - TG-DTA
KW - nonparametric kinetics
ER -

BibTex
@article{RevCh2017P2734,
author = {Dumitras Mihai and Maftei Dan and Airinei Anton and Tudorachi Nita and Dirtu Alin Constantin},
title = {NPK Analysis of the Thermal Degradation of Decabromodiphenylether},
journal = {Revista de Chimie},
volume = {68},
number = {11},
pages = {2734-2738},
year = {2017},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.17.11.5965},
url = {https://revistadechimie.ro/Articles.asp?ID=5965}
}

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