Possible Pathway for Ifosfamide Degradation via Fe-TiO2 Assisted Photo Catalysis

Constantin, Lucian Alexandru; Constantin, Mirela Alina; Nitoi, Ines; Chiriac, Florentina Laura; Galaon, Toma; Cristea, Nicolae Ionut

Lucian Alexandru Constantin, Mirela Alina Constantin, Ines Nitoi, Florentina Laura Chiriac, Toma Galaon, Nicolae Ionut Cristea

Possible Pathway for Ifosfamide Degradation via Fe-TiO2 Assisted Photo Catalysis

Abstract:

Ifosfamide (IF) degradation from aqueous system via UV-Vis Fe-TiO2 system was studied for a photo catalyst dose of 200 mg/L and an irradiation time up to 240 min. IF degradation efficiency was monitored via Liquid Chromatography-Mass Spectrometry technique (LC-MS). Experimental photocatalytic tests were performed both in the absence and presence of 2-propanol and F- radicals’ scavengers and the results proved that IF degradation occurs most likely in the bulk solution. Experimental results showed that degradation efficiencies for IF varied between 39.52% in the presence of 2-propanol and 70.70% in the scavengers’ absence. Six degradation intermediates were identified using the same LC-MS technique and a three stage degradation pathway was proposed based on both available literature data and evolution of degradation intermediates peaks.

Keywords:
Fe doped TiO2; ifosfamide; heterogeneous photo catalysis; degradation intermediates

Issue: 2018, Volume 69, Issue 11

Pages: 3234-3237

Publication date: 2018/12/15

https://doi.org/10.37358/RC.18.11.6720

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This article is published under the Creative Commons Attribution 4.0 International License

Citation Styles

Cite this article as:
CONSTANTIN, L.A., CONSTANTIN, M.A., NITOI, I., CHIRIAC, F.L., GALAON, T., CRISTEA, N.I., Possible Pathway for Ifosfamide Degradation via Fe-TiO2 Assisted Photo Catalysis, Rev. Chim., 69(11), 2018, 3234-3237.

Vancouver
Constantin LA, Constantin MA, Nitoi I, Chiriac FL, Galaon T, Cristea NI. Possible Pathway for Ifosfamide Degradation via Fe-TiO2 Assisted Photo Catalysis. Rev. Chim.[internet]. 2018 Nov;69(11):3234-3237. Available from: https://doi.org/10.37358/RC.18.11.6720

APA 6th edition
Constantin, L.A., Constantin, M.A., Nitoi, I., Chiriac, F.L., Galaon, T. & Cristea, N.I. (2018). Possible Pathway for Ifosfamide Degradation via Fe-TiO2 Assisted Photo Catalysis. Revista de Chimie, 69(11), 3234-3237. https://doi.org/10.37358/RC.18.11.6720

Harvard
Constantin, L.A., Constantin, M.A., Nitoi, I., Chiriac, F.L., Galaon, T., Cristea, N.I. (2018). 'Possible Pathway for Ifosfamide Degradation via Fe-TiO2 Assisted Photo Catalysis', Revista de Chimie, 69(11), pp. 3234-3237. https://doi.org/10.37358/RC.18.11.6720

IEEE
L.A. Constantin, M.A. Constantin, I. Nitoi, F.L. Chiriac, T. Galaon, N.I. Cristea, "Possible Pathway for Ifosfamide Degradation via Fe-TiO2 Assisted Photo Catalysis". Revista de Chimie, vol. 69, no. 11, pp. 3234-3237, 2018. [online]. https://doi.org/10.37358/RC.18.11.6720

Text
Lucian Alexandru Constantin, Mirela Alina Constantin, Ines Nitoi, Florentina Laura Chiriac, Toma Galaon, Nicolae Ionut Cristea,
Possible Pathway for Ifosfamide Degradation via Fe-TiO2 Assisted Photo Catalysis,
Revista de Chimie,
Volume 69, Issue 11,
2018,
Pages 3234-3237,
ISSN 2668-8212,
https://doi.org/10.37358/RC.18.11.6720.
(https://revistadechimie.ro/Articles.asp?ID=6720)
Keywords: Fe doped TiO2; ifosfamide; heterogeneous photo catalysis; degradation intermediates

RIS
TY - JOUR
T1 - Possible Pathway for Ifosfamide Degradation via Fe-TiO2 Assisted Photo Catalysis
A1 - Constantin, Lucian Alexandru
A2 - Constantin, Mirela Alina
A3 - Nitoi, Ines
A4 - Chiriac, Florentina Laura
A5 - Galaon, Toma
A6 - Cristea, Nicolae Ionut
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2018
VL - 69
IS - 11
SP - 3234
EP - 3237
UR - https://doi.org/10.37358/RC.18.11.6720
KW - Fe doped TiO2
KW - ifosfamide
KW - heterogeneous photo catalysis
KW - degradation intermediates
ER -

BibTex
@article{RevCh2018P3234,
author = {Constantin Lucian Alexandru and Constantin Mirela Alina and Nitoi Ines and Chiriac Florentina Laura and Galaon Toma and Cristea Nicolae Ionut},
title = {Possible Pathway for Ifosfamide Degradation via Fe-TiO2 Assisted Photo Catalysis},
journal = {Revista de Chimie},
volume = {69},
number = {11},
pages = {3234-3237},
year = {2018},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.18.11.6720},
url = {https://revistadechimie.ro/Articles.asp?ID=6720}
}

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