Hydroconversion of Residual Fatty Acids on a Molybdenum-Copper Catalyst

Ion, Dan; BomboȘ, Mihaela; Vasilievici, Gabriel; Radu, Adrian; RoȘca, Paul

Dan Ion, Mihaela BomboȘ, Gabriel Vasilievici, Adrian Radu, Paul RoȘca

Hydroconversion of Residual Fatty Acids on a Molybdenum-Copper Catalyst

Abstract:

The molybdenum-copper catalyst was prepared by impregnating with an aqueous precursors solution by the pore filling method. The catalyst was characterized by determining the acid strength and textural characteristics. The catalyst contains predominantly weak acidic centers and the average pore diameter is 4.3 nm. Conversion of residual fatty acids into deoxygenated liquid were carried out on a laboratory equipment in continuous system using a fixed bed catalytic reactor. The reaction products where mainly linear hydrocarbons C15, C16, C17 and C18 and shorter chain hydrocarbons [C15 and no oxygenated products, alkene or iso-alkane were identified. The yield in hydrocarbons obtained by decarboxylation / decarbonylation and by hydrocraking are lower than the yield in hydrocarbons obtained by hydrodeoxygenation.

Keywords:
residual fatty acids; biofuel; hydroconversion; catalyst acidity; Co; Mo; gama-Al2O3

Issue: 2019, Volume 70, Issue 12

Pages: 4266-4274

Publication date: 2020/1/20

https://doi.org/10.37358/RC.19.12.7744

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This article is published under the Creative Commons Attribution 4.0 International License

Citation Styles

Cite this article as:
ION, D., BOMBOȘ, M., VASILIEVICI, G., RADU, A., ROȘCA, P., Hydroconversion of Residual Fatty Acids on a Molybdenum-Copper Catalyst, Rev. Chim., 70(12), 2019, 4266-4274.

Vancouver
Ion D, BomboȘ M, Vasilievici G, Radu A, RoȘca P. Hydroconversion of Residual Fatty Acids on a Molybdenum-Copper Catalyst. Rev. Chim.[internet]. 2019 Dec;70(12):4266-4274. Available from: https://doi.org/10.37358/RC.19.12.7744

APA 6th edition
Ion, D., BomboȘ, M., Vasilievici, G., Radu, A. & RoȘca, P. (2019). Hydroconversion of Residual Fatty Acids on a Molybdenum-Copper Catalyst. Revista de Chimie, 70(12), 4266-4274. https://doi.org/10.37358/RC.19.12.7744

Harvard
Ion, D., BomboȘ, M., Vasilievici, G., Radu, A., RoȘca, P. (2019). 'Hydroconversion of Residual Fatty Acids on a Molybdenum-Copper Catalyst', Revista de Chimie, 70(12), pp. 4266-4274. https://doi.org/10.37358/RC.19.12.7744

IEEE
D. Ion, M. BomboȘ, G. Vasilievici, A. Radu, P. RoȘca, "Hydroconversion of Residual Fatty Acids on a Molybdenum-Copper Catalyst". Revista de Chimie, vol. 70, no. 12, pp. 4266-4274, 2019. [online]. https://doi.org/10.37358/RC.19.12.7744

Text
Dan Ion, Mihaela BomboȘ, Gabriel Vasilievici, Adrian Radu, Paul RoȘca,
Hydroconversion of Residual Fatty Acids on a Molybdenum-Copper Catalyst,
Revista de Chimie,
Volume 70, Issue 12,
2019,
Pages 4266-4274,
ISSN 2668-8212,
https://doi.org/10.37358/RC.19.12.7744.
(https://revistadechimie.ro/Articles.asp?ID=7744)
Keywords: residual fatty acids; biofuel; hydroconversion; catalyst acidity; Co; Mo; gama-Al2O3

RIS
TY - JOUR
T1 - Hydroconversion of Residual Fatty Acids on a Molybdenum-Copper Catalyst
A1 - Ion, Dan
A2 - BomboȘ, Mihaela
A3 - Vasilievici, Gabriel
A4 - Radu, Adrian
A5 - RoȘca, Paul
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2019
VL - 70
IS - 12
SP - 4266
EP - 4274
UR - https://doi.org/10.37358/RC.19.12.7744
KW - residual fatty acids
KW - biofuel
KW - hydroconversion
KW - catalyst acidity
KW - Co
KW - Mo
KW - gama-Al2O3
ER -

BibTex
@article{RevCh2019P4266,
author = {Ion Dan and BomboȘ Mihaela and Vasilievici Gabriel and Radu Adrian and RoȘca Paul},
title = {Hydroconversion of Residual Fatty Acids on a Molybdenum-Copper Catalyst},
journal = {Revista de Chimie},
volume = {70},
number = {12},
pages = {4266-4274},
year = {2019},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.19.12.7744},
url = {https://revistadechimie.ro/Articles.asp?ID=7744}
}

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