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Revista de Chimie, Volume 71, Issue 1, pp. 201-205 (2020)
https://doi.org/10.37358/RC.20.1.7832

Adriana-Maria Andreica, Lucia Gansca, Irina Ciotlaus, Ioan Oprean

A New Synthesis of the Sex Pheromone of the Indian Meal Moth Plodia Interpunctella hb. (Lepidoptera, Pyralidae)

Abstract:

New synthesis of (9Z,12E)-9,12-tetradecadien-1-yl acetate, the sex pheromone of the indian meal moth Plodia interpunctella (Lepidoptera, Pyralidae), were developed. The synthesis was based on a C8+C2=C10 and C10+C4=C14 coupling scheme. The route involves, as the key step, the use of the mercury derivative of the terminal-alkyne -functionalised as intermediate.The first coupling reaction took place between 1-tert-butoxy-8-bromo-octane and lithium acetylide-ethylendiamine complex obtaining 1-tert-butoxy-dec-9-yne, which is transformed in dimercury.In the second coupling reaction, the mercury derivative was directly lithiated and then alkylated with (E)-1-bromo-2-butene obtaining 1-tert-butoxy-(9-yne,12E)-9,12-tetradecaenyne. After stereoselective reduction in the presence of NiP-2 catalyst and acetylation gave (9Z,12E)-9,12-tetradecadien-1-yl acetate with 82% isomeric purity.
Keywords:
(9Z;12E)-9;12-tetradecadien-1-yl acetate; Lepidoptera; sex pheromone; Plodia interpunctella

Issue: 2020 Volume 71, Number 1
Pages: 201-205
https://doi.org/10.37358/RC.20.1.7832
download pdf   Download Pdf Article
Citation Styles
Cite this article as:
ANDREICA, A., GANSCA, L., CIOTLAUS, I., OPREAN, I., Rev.Chim., 71, no. 1, 2020, p. 201

Vancouver
Andreica A, Gansca L, Ciotlaus I, Oprean I. A New Synthesis of the Sex Pheromone of the Indian Meal Moth Plodia Interpunctella hb. (Lepidoptera, Pyralidae). Rev. Chim.[internet]. 2020 Jan;71(1):201-205. Available from: https://doi.org/10.37358/RC.20.1.7832


APA 6th edition
Andreica, A., Gansca, L., Ciotlaus, I. & Oprean, I. (2020). A New Synthesis of the Sex Pheromone of the Indian Meal Moth Plodia Interpunctella hb. (Lepidoptera, Pyralidae). Revista de Chimie, 71(1), 201-205. https://doi.org/10.37358/RC.20.1.7832


Harvard
Andreica, A., Gansca, L., Ciotlaus, I., Oprean, I. (2020). 'A New Synthesis of the Sex Pheromone of the Indian Meal Moth Plodia Interpunctella hb. (Lepidoptera, Pyralidae)', Revista de Chimie, 71(1), pp. 201-205. https://doi.org/10.37358/RC.20.1.7832


IEEE
A. Andreica, L. Gansca, I. Ciotlaus, I. Oprean, "A New Synthesis of the Sex Pheromone of the Indian Meal Moth Plodia Interpunctella hb. (Lepidoptera, Pyralidae)". Revista de Chimie, vol. 71, no. 1, pp. 201-205, 2020. [online]. https://doi.org/10.37358/RC.20.1.7832


Text
Adriana-Maria Andreica, Lucia Gansca, Irina Ciotlaus, Ioan Oprean,
A New Synthesis of the Sex Pheromone of the Indian Meal Moth Plodia Interpunctella hb. (Lepidoptera, Pyralidae),
Revista de Chimie,
Volume 71, Issue 1,
2020,
Pages 201-205,
ISSN 2668-8212,
https://doi.org/10.37358/RC.20.1.7832.
(https://revistadechimie.ro/Articles.asp?ID=7832)
Keywords: (9Z;12E)-9;12-tetradecadien-1-yl acetate; Lepidoptera; sex pheromone; Plodia interpunctella


RIS
TY - JOUR
T1 - A New Synthesis of the Sex Pheromone of the Indian Meal Moth Plodia Interpunctella hb. (Lepidoptera, Pyralidae)
A1 - Andreica, Adriana-Maria
A2 - Gansca, Lucia
A3 - Ciotlaus, Irina
A4 - Oprean, Ioan
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2020
VL - 71
IS - 1
SP - 201
EP - 205
UR - https://doi.org/10.37358/RC.20.1.7832
KW - (9Z
KW - 12E)-9
KW - 12-tetradecadien-1-yl acetate
KW - Lepidoptera
KW - sex pheromone
KW - Plodia interpunctella
ER -


BibTex
@article{RevCh2020P201,
author = {Andreica Adriana-Maria and Gansca Lucia and Ciotlaus Irina and Oprean Ioan},
title = {A New Synthesis of the Sex Pheromone of the Indian Meal Moth Plodia Interpunctella hb. (Lepidoptera, Pyralidae)},
journal = {Revista de Chimie},
volume = {71},
number = {1},
pages = {201-205},
year = {2020},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.20.1.7832},
url = {https://revistadechimie.ro/Articles.asp?ID=7832}
}
 
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