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REVISTA DE CHIMIE
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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2020, Volume 71, Issue 9, 98-112

https://doi.org/10.37358/RC.20.9.8321

Shanmugam Palanisamy, Kannan Kandasamy

Direct Hydrogenation and Hydrotreating of Neat Vegetal Oil into Renewable Diesel Using Alumina Binder with Zeolite

Abstract:

Hydrodeoxygenation of vegetal oil and methyl oleate studied using Pt and Pd supported with alumina-beta-zeolite (a-Al2O3-H-a) and comparing its performance with NiMo/a-Al2O3 and Pd/C in a semi-batch reactor, at 300 - 340 oC and 2.0 MPa. This study has used Pd and Pt on H-a zeolites with alumina binder as extrudate and it examines over triglycerides hydrogenolysis. Pd/C showed higher rate of deoxygenation and the selectivity of C18/C17 was higher for NiMo-S/a-Al2O3 and PdPt/a-Al2O3-H-a. PdPt/a-Al2O3-H-a enhanced the hydrogenation and hydrogenolysis, while conversion and yield in deoxygenation and decomposition has reached identicical performance as NiMo-S/a-Al2O3 catalytic deoxygenation process. Both the thermal decomposition and the hydrogenation of unsaturated triglycerides were mainly affected by H2 partial pressure. Transition metals like Pd and Pt on H-a and alumina binder ratio of 40:60 wt% showed effective hydrodeoxygenation of vegetal oil without substituting sulfur feed.
Keywords:
Hydroprocessing; Vegetal oil; Alumina; Carbon; Zeolite

Issue: 2020, Volume 71, Issue 9
Pages: 98-112
Publication date: 2020/9/5
https://doi.org/10.37358/RC.20.9.8321
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Creative Commons License
This article is published under the Creative Commons Attribution 4.0 International License
Citation Styles
Cite this article as:
PALANISAMY, S., KANDASAMY, K., Direct Hydrogenation and Hydrotreating of Neat Vegetal Oil into Renewable Diesel Using Alumina Binder with Zeolite, Rev. Chim., 71(9), 2020, 98-112.

Vancouver
Palanisamy S, Kandasamy K. Direct Hydrogenation and Hydrotreating of Neat Vegetal Oil into Renewable Diesel Using Alumina Binder with Zeolite. Rev. Chim.[internet]. 2020 Sep;71(9):98-112. Available from: https://doi.org/10.37358/RC.20.9.8321


APA 6th edition
Palanisamy, S., Kandasamy, K. (2020). Direct Hydrogenation and Hydrotreating of Neat Vegetal Oil into Renewable Diesel Using Alumina Binder with Zeolite. Revista de Chimie, 71(9), 98-112. https://doi.org/10.37358/RC.20.9.8321


Harvard
Palanisamy, S., Kandasamy, K. (2020). 'Direct Hydrogenation and Hydrotreating of Neat Vegetal Oil into Renewable Diesel Using Alumina Binder with Zeolite', Revista de Chimie, 71(9), pp. 98-112. https://doi.org/10.37358/RC.20.9.8321


IEEE
S. Palanisamy, K. Kandasamy, "Direct Hydrogenation and Hydrotreating of Neat Vegetal Oil into Renewable Diesel Using Alumina Binder with Zeolite". Revista de Chimie, vol. 71, no. 9, pp. 98-112, 2020. [online]. https://doi.org/10.37358/RC.20.9.8321


Text
Shanmugam Palanisamy, Kannan Kandasamy,
Direct Hydrogenation and Hydrotreating of Neat Vegetal Oil into Renewable Diesel Using Alumina Binder with Zeolite,
Revista de Chimie,
Volume 71, Issue 9,
2020,
Pages 98-112,
ISSN 2668-8212,
https://doi.org/10.37358/RC.20.9.8321.
(https://revistadechimie.ro/Articles.asp?ID=8321)
Keywords: Hydroprocessing; Vegetal oil; Alumina; Carbon; Zeolite


RIS
TY - JOUR
T1 - Direct Hydrogenation and Hydrotreating of Neat Vegetal Oil into Renewable Diesel Using Alumina Binder with Zeolite
A1 - Palanisamy, Shanmugam
A2 - Kandasamy, Kannan
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2020
VL - 71
IS - 9
SP - 98
EP - 112
UR - https://doi.org/10.37358/RC.20.9.8321
KW - Hydroprocessing
KW - Vegetal oil
KW - Alumina
KW - Carbon
KW - Zeolite
ER -


BibTex
@article{RevCh2020P98,
author = {Palanisamy Shanmugam and Kandasamy Kannan},
title = {Direct Hydrogenation and Hydrotreating of Neat Vegetal Oil into Renewable Diesel Using Alumina Binder with Zeolite},
journal = {Revista de Chimie},
volume = {71},
number = {9},
pages = {98-112},
year = {2020},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.20.9.8321},
url = {https://revistadechimie.ro/Articles.asp?ID=8321}
}
 
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