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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2020, Volume 71, Issue 9, 143-152

https://doi.org/10.37358/RC.20.9.8324

Ayowole O. Ayeni, Gareth M. Watkins, Eric C. Hosten

Impact of Thiocyanate on Catalytic Abilities of Metal Complexes of 4-N-(4-hydroxy-3-((piperidin-1-yl)methyl) phenyl)acetamide (HL). X-ray Crystal Structure of HL

Abstract:

Four new [copper(II) and iron(III)] complexes were synthesized using N-(4-hydroxy-3-((piperidin-1-yl)methyl)phenyl)acetamide (HL) a Mannich base as ligand. All compounds were successfully characterized by elemental analysis, conductivity measurements, Ultraviolet-visible, Infrared, and Nuclear Magnetic Resonance spectroscopy. Furthermore, the structural determination of HL by X-ray diffraction technique at room temperature showed that the ligand crystallized in the monoclinic crystal system with space group Cc and Z=4. Structural analysis revealed the chelation of the ligand and the bonding mode of the thiocyanate group. All the metal complexes demonstrated considerable abilities to oxidize 3, 5-di-tert-butylcatechol in DMF under aerobic conditions. Complex 3 (with an iron(III) center) displayed the highest turnover rate of 14.69 ± 0.71 h-1.
Keywords:
p-acetamidophenol; copper(II); iron(III); biomimetic; thiocyanate

Issue: 2020, Volume 71, Issue 9
Pages: 143-152
Publication date: 2020/9/5
https://doi.org/10.37358/RC.20.9.8324
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Creative Commons License
This article is published under the Creative Commons Attribution 4.0 International License
Citation Styles
Cite this article as:
AYENI, A.O., WATKINS, G.M., HOSTEN, E.C., Impact of Thiocyanate on Catalytic Abilities of Metal Complexes of 4-N-(4-hydroxy-3-((piperidin-1-yl)methyl) phenyl)acetamide (HL). X-ray Crystal Structure of HL, Rev. Chim., 71(9), 2020, 143-152.

Vancouver
Ayeni AO, Watkins GM, Hosten EC. Impact of Thiocyanate on Catalytic Abilities of Metal Complexes of 4-N-(4-hydroxy-3-((piperidin-1-yl)methyl) phenyl)acetamide (HL). X-ray Crystal Structure of HL. Rev. Chim.[internet]. 2020 Sep;71(9):143-152. Available from: https://doi.org/10.37358/RC.20.9.8324


APA 6th edition
Ayeni, A.O., Watkins, G.M. & Hosten, E.C. (2020). Impact of Thiocyanate on Catalytic Abilities of Metal Complexes of 4-N-(4-hydroxy-3-((piperidin-1-yl)methyl) phenyl)acetamide (HL). X-ray Crystal Structure of HL. Revista de Chimie, 71(9), 143-152. https://doi.org/10.37358/RC.20.9.8324


Harvard
Ayeni, A.O., Watkins, G.M., Hosten, E.C. (2020). 'Impact of Thiocyanate on Catalytic Abilities of Metal Complexes of 4-N-(4-hydroxy-3-((piperidin-1-yl)methyl) phenyl)acetamide (HL). X-ray Crystal Structure of HL', Revista de Chimie, 71(9), pp. 143-152. https://doi.org/10.37358/RC.20.9.8324


IEEE
A.O. Ayeni, G.M. Watkins, E.C. Hosten, "Impact of Thiocyanate on Catalytic Abilities of Metal Complexes of 4-N-(4-hydroxy-3-((piperidin-1-yl)methyl) phenyl)acetamide (HL). X-ray Crystal Structure of HL". Revista de Chimie, vol. 71, no. 9, pp. 143-152, 2020. [online]. https://doi.org/10.37358/RC.20.9.8324


Text
Ayowole O. Ayeni, Gareth M. Watkins, Eric C. Hosten,
Impact of Thiocyanate on Catalytic Abilities of Metal Complexes of 4-N-(4-hydroxy-3-((piperidin-1-yl)methyl) phenyl)acetamide (HL). X-ray Crystal Structure of HL,
Revista de Chimie,
Volume 71, Issue 9,
2020,
Pages 143-152,
ISSN 2668-8212,
https://doi.org/10.37358/RC.20.9.8324.
(https://revistadechimie.ro/Articles.asp?ID=8324)
Keywords: p-acetamidophenol; copper(II); iron(III); biomimetic; thiocyanate


RIS
TY - JOUR
T1 - Impact of Thiocyanate on Catalytic Abilities of Metal Complexes of 4-N-(4-hydroxy-3-((piperidin-1-yl)methyl) phenyl)acetamide (HL). X-ray Crystal Structure of HL
A1 - Ayeni, Ayowole O.
A2 - Watkins, Gareth M.
A3 - Hosten, Eric C.
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2020
VL - 71
IS - 9
SP - 143
EP - 152
UR - https://doi.org/10.37358/RC.20.9.8324
KW - p-acetamidophenol
KW - copper(II)
KW - iron(III)
KW - biomimetic
KW - thiocyanate
ER -


BibTex
@article{RevCh2020P143,
author = {Ayeni Ayowole O. and Watkins Gareth M. and Hosten Eric C.},
title = {Impact of Thiocyanate on Catalytic Abilities of Metal Complexes of 4-N-(4-hydroxy-3-((piperidin-1-yl)methyl) phenyl)acetamide (HL). X-ray Crystal Structure of HL},
journal = {Revista de Chimie},
volume = {71},
number = {9},
pages = {143-152},
year = {2020},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.20.9.8324},
url = {https://revistadechimie.ro/Articles.asp?ID=8324}
}
 
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