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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2020, Volume 71, Issue 12, 1-9

https://doi.org/10.37358/RC.20.12.8381

Liviu Birzan, Victorita Tecuceanu, Mihaela Cristea, Constantin C. Draghici, Anamaria Hanganu, Alexandru C. Razus

New Benzo- and Dibenzo-Crown Ethers with (Azulen-1-yl)Vinyl Substituents

Abstract:

Several 1-azulenyl vinyl crown ethers were synthesized starting from (1-azulenylmethyl) triphenylphosphonium iodide and 4-formylbenzo-crown ethers in the Wittig reaction conditions. The reaction worked in fair conditions and the obtained mixtures of geometric isomers were separated using column chromatography. The isomers were identified using 1H-NMR spectra and the mass spectra were recorded using ESI. The UV-vis spectra showed bathochromic effect in Z isomer compared with the E one.
Keywords:
azulene; crown ethers; Wittig reaction; NMR spectra

Issue: 2020, Volume 71, Issue 12
Pages: 1-9
Publication date: 2021/1/7
https://doi.org/10.37358/RC.20.12.8381
download pdf   Download Pdf Article
Creative Commons License
This article is published under the Creative Commons Attribution 4.0 International License
Citation Styles
Cite this article as:
BIRZAN, L., TECUCEANU, V., CRISTEA, M., DRAGHICI, C.C., HANGANU, A., RAZUS, A.C., New Benzo- and Dibenzo-Crown Ethers with (Azulen-1-yl)Vinyl Substituents, Rev. Chim., 71(12), 2020, 1-9.

Vancouver
Birzan L, Tecuceanu V, Cristea M, Draghici CC, Hanganu A, Razus AC. New Benzo- and Dibenzo-Crown Ethers with (Azulen-1-yl)Vinyl Substituents. Rev. Chim.[internet]. 2020 Dec;71(12):1-9. Available from: https://doi.org/10.37358/RC.20.12.8381


APA 6th edition
Birzan, L., Tecuceanu, V., Cristea, M., Draghici, C.C., Hanganu, A. & Razus, A.C. (2020). New Benzo- and Dibenzo-Crown Ethers with (Azulen-1-yl)Vinyl Substituents. Revista de Chimie, 71(12), 1-9. https://doi.org/10.37358/RC.20.12.8381


Harvard
Birzan, L., Tecuceanu, V., Cristea, M., Draghici, C.C., Hanganu, A., Razus, A.C. (2020). 'New Benzo- and Dibenzo-Crown Ethers with (Azulen-1-yl)Vinyl Substituents', Revista de Chimie, 71(12), pp. 1-9. https://doi.org/10.37358/RC.20.12.8381


IEEE
L. Birzan, V. Tecuceanu, M. Cristea, C.C. Draghici, A. Hanganu, A.C. Razus, "New Benzo- and Dibenzo-Crown Ethers with (Azulen-1-yl)Vinyl Substituents". Revista de Chimie, vol. 71, no. 12, pp. 1-9, 2020. [online]. https://doi.org/10.37358/RC.20.12.8381


Text
Liviu Birzan, Victorita Tecuceanu, Mihaela Cristea, Constantin C. Draghici, Anamaria Hanganu, Alexandru C. Razus,
New Benzo- and Dibenzo-Crown Ethers with (Azulen-1-yl)Vinyl Substituents,
Revista de Chimie,
Volume 71, Issue 12,
2020,
Pages 1-9,
ISSN 2668-8212,
https://doi.org/10.37358/RC.20.12.8381.
(https://revistadechimie.ro/Articles.asp?ID=8381)
Keywords: azulene; crown ethers; Wittig reaction; NMR spectra


RIS
TY - JOUR
T1 - New Benzo- and Dibenzo-Crown Ethers with (Azulen-1-yl)Vinyl Substituents
A1 - Birzan, Liviu
A2 - Tecuceanu, Victorita
A3 - Cristea, Mihaela
A4 - Draghici, Constantin C.
A5 - Hanganu, Anamaria
A6 - Razus, Alexandru C.
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2020
VL - 71
IS - 12
SP - 1
EP - 9
UR - https://doi.org/10.37358/RC.20.12.8381
KW - azulene
KW - crown ethers
KW - Wittig reaction
KW - NMR spectra
ER -


BibTex
@article{RevCh2020P1,
author = {Birzan Liviu and Tecuceanu Victorita and Cristea Mihaela and Draghici Constantin C. and Hanganu Anamaria and Razus Alexandru C.},
title = {New Benzo- and Dibenzo-Crown Ethers with (Azulen-1-yl)Vinyl Substituents},
journal = {Revista de Chimie},
volume = {71},
number = {12},
pages = {1-9},
year = {2020},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.20.12.8381},
url = {https://revistadechimie.ro/Articles.asp?ID=8381}
}
 
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