Effect of Alkaline Concentrations on the Synthesis of Volcanic Soil-Based Zeolite for Methylene Blue Removal by Fenton-Like Oxidation Process

Abidin, Zaenal; Prajaputra, Vicky; Budiarti, Sri; Suryaningtyas, Dyah Tjahyandari; Matsue, Naoto; Sakakibara, Masayuki

Zaenal Abidin, Vicky Prajaputra, Sri Budiarti, Dyah Tjahyandari Suryaningtyas, Naoto Matsue, Masayuki Sakakibara

Effect of Alkaline Concentrations on the Synthesis of Volcanic Soil-Based Zeolite for Methylene Blue Removal by Fenton-Like Oxidation Process

Abstract:

This study demonstrated the potential use of volcanic ash soil (VAS) as raw materials for synthesizing zeolite without adding any templates or seeds. Here we investigated the effect of alkaline concentrations on the synthesis of VAS-based zeolite and enhanced its ability for methylene blue (MB) removal by Fenton-like process. Zeolite was directly synthesized by mixing the VAS within alkaline concentrations of 0.5 mol/L(P1), 1.5 mol/L (P2), and 3.0 mol/L (P3), respectively, followed by a simple hydrothermal procedure at 100 oC for 24 hours. The synthesized product characteristics were obtained from the Fourier transform infrared (FTIR) and X-ray diffraction (XRD) analysis, which confirmed the formation of zeolite type A and some mineral phases in the P2 and P3 samples. The mentioned samples reached equilibrium state at MB concentration of 200 mg/L with high adsorption capacity values compared to VAS. The adsorption showed a better fit to the Langmuir isotherm model (R2]0.999), in which the maximum uptake capacities were found to be 24.03 mg/g for P2 and 14.30 mg/g for P3. Interestingly, the percentage of MB removal using P2 and P3 increased greatly from 52.81% and 32.26% to 98.92% and 98.85% by Fenton-like process, respectively.

Keywords:
adsorption; catalytic; degradation; fenton-like oxidation; volcanic soil; zeolite

Issue: 2020, Volume 71, Issue 12

Pages: 47-55

Publication date: 2021/1/7

https://doi.org/10.37358/RC.20.12.8385

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This article is published under the Creative Commons Attribution 4.0 International License

Citation Styles

Cite this article as:
ABIDIN, Z., PRAJAPUTRA, V., BUDIARTI, S., SURYANINGTYAS, D.T., MATSUE, N., SAKAKIBARA, M., Effect of Alkaline Concentrations on the Synthesis of Volcanic Soil-Based Zeolite for Methylene Blue Removal by Fenton-Like Oxidation Process, Rev. Chim., 71(12), 2020, 47-55.

Vancouver
Abidin Z, Prajaputra V, Budiarti S, Suryaningtyas DT, Matsue N, Sakakibara M. Effect of Alkaline Concentrations on the Synthesis of Volcanic Soil-Based Zeolite for Methylene Blue Removal by Fenton-Like Oxidation Process. Rev. Chim.[internet]. 2020 Dec;71(12):47-55. Available from: https://doi.org/10.37358/RC.20.12.8385

APA 6th edition
Abidin, Z., Prajaputra, V., Budiarti, S., Suryaningtyas, D.T., Matsue, N. & Sakakibara, M. (2020). Effect of Alkaline Concentrations on the Synthesis of Volcanic Soil-Based Zeolite for Methylene Blue Removal by Fenton-Like Oxidation Process. Revista de Chimie, 71(12), 47-55. https://doi.org/10.37358/RC.20.12.8385

Harvard
Abidin, Z., Prajaputra, V., Budiarti, S., Suryaningtyas, D.T., Matsue, N., Sakakibara, M. (2020). 'Effect of Alkaline Concentrations on the Synthesis of Volcanic Soil-Based Zeolite for Methylene Blue Removal by Fenton-Like Oxidation Process', Revista de Chimie, 71(12), pp. 47-55. https://doi.org/10.37358/RC.20.12.8385

IEEE
Z. Abidin, V. Prajaputra, S. Budiarti, D.T. Suryaningtyas, N. Matsue, M. Sakakibara, "Effect of Alkaline Concentrations on the Synthesis of Volcanic Soil-Based Zeolite for Methylene Blue Removal by Fenton-Like Oxidation Process". Revista de Chimie, vol. 71, no. 12, pp. 47-55, 2020. [online]. https://doi.org/10.37358/RC.20.12.8385

Text
Zaenal Abidin, Vicky Prajaputra, Sri Budiarti, Dyah Tjahyandari Suryaningtyas, Naoto Matsue, Masayuki Sakakibara,
Effect of Alkaline Concentrations on the Synthesis of Volcanic Soil-Based Zeolite for Methylene Blue Removal by Fenton-Like Oxidation Process,
Revista de Chimie,
Volume 71, Issue 12,
2020,
Pages 47-55,
ISSN 2668-8212,
https://doi.org/10.37358/RC.20.12.8385.
(https://revistadechimie.ro/Articles.asp?ID=8385)
Keywords: adsorption; catalytic; degradation; fenton-like oxidation; volcanic soil; zeolite

RIS
TY - JOUR
T1 - Effect of Alkaline Concentrations on the Synthesis of Volcanic Soil-Based Zeolite for Methylene Blue Removal by Fenton-Like Oxidation Process
A1 - Abidin, Zaenal
A2 - Prajaputra, Vicky
A3 - Budiarti, Sri
A4 - Suryaningtyas, Dyah Tjahyandari
A5 - Matsue, Naoto
A6 - Sakakibara, Masayuki
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2020
VL - 71
IS - 12
SP - 47
EP - 55
UR - https://doi.org/10.37358/RC.20.12.8385
KW - adsorption
KW - catalytic
KW - degradation
KW - fenton-like oxidation
KW - volcanic soil
KW - zeolite
ER -

BibTex
@article{RevCh2020P47,
author = {Abidin Zaenal and Prajaputra Vicky and Budiarti Sri and Suryaningtyas Dyah Tjahyandari and Matsue Naoto and Sakakibara Masayuki},
title = {Effect of Alkaline Concentrations on the Synthesis of Volcanic Soil-Based Zeolite for Methylene Blue Removal by Fenton-Like Oxidation Process},
journal = {Revista de Chimie},
volume = {71},
number = {12},
pages = {47-55},
year = {2020},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.20.12.8385},
url = {https://revistadechimie.ro/Articles.asp?ID=8385}
}

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