Catalytic Performance of Phosphorus Incorporated HZSM-5 in Coupling Transformation of Methanol with 1-butene to Propylene

Tian, Haifeng; Nan, Yongyong; Lv, Jinlong; Zha, Fei; Tang, Xiaohua; Chang, Yue; Guo, Xiaojun

Haifeng Tian, Yongyong Nan, Jinlong Lv, Fei Zha, Xiaohua Tang, Yue Chang, Xiaojun Guo

Catalytic Performance of Phosphorus Incorporated HZSM-5 in Coupling Transformation of Methanol with 1-butene to Propylene

Abstract:

Directly incorporated phosphorus species into the framework of HZSM-5 zeolite (H[P, Al]-ZSM-5) was successfully synthesized by the facile hydrothermal method. It was characterized by employing XRD, ICP-OES, SEM, FT-IR, N2 adsorption-desorption, NH3-TPD, XPS and TG-DTA, respectively. The effects of the phosphorus species content, temperature, WHSV, and the molar ratio of methanol/1-butene in coupling transformation of methanol with 1-butene to propylene catalyzed by H[P, Al]-ZSM-5 in a fixed bed reactor were studied systematically. Tests have suggested the acid content and specific surface area of H[P, Al]-ZSM-5 are reduced. Under the condition of reaction temperature at 550Z, molar ratio of methanol/1-butene to 1.0, reaction pressure at 0.1 MPa and WHSV= 3.53 h-1, the P-modified HZSM-5 zeolite (with the P2O5 molar composition of 0.4 )the selectivity and yield of propylene are 35.6% and 32.5%, respectively.

Keywords:
The P-modified HZSM-5 zeolite; Coupling ;methanol ;1-butene; Propylene

Issue: 2021, Volume 72, Issue 3

Pages: 33-44

Publication date: 2021/7/29

https://doi.org/10.37358/RC.21.3.8435

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This article is published under the Creative Commons Attribution 4.0 International License

Citation Styles

Cite this article as:
TIAN, H., NAN, Y., LV, J., ZHA, F., TANG, X., CHANG, Y., GUO, X., Catalytic Performance of Phosphorus Incorporated HZSM-5 in Coupling Transformation of Methanol with 1-butene to Propylene, Rev. Chim., 72(3), 2021, 33-44.

Vancouver
Tian H, Nan Y, Lv J, Zha F, Tang X, Chang Y, Guo X. Catalytic Performance of Phosphorus Incorporated HZSM-5 in Coupling Transformation of Methanol with 1-butene to Propylene. Rev. Chim.[internet]. 2021 Mar;72(3):33-44. Available from: https://doi.org/10.37358/RC.21.3.8435

APA 6th edition
Tian, H., Nan, Y., Lv, J., Zha, F., Tang, X., Chang, Y. & Guo, X. (2021). Catalytic Performance of Phosphorus Incorporated HZSM-5 in Coupling Transformation of Methanol with 1-butene to Propylene. Revista de Chimie, 72(3), 33-44. https://doi.org/10.37358/RC.21.3.8435

Harvard
Tian, H., Nan, Y., Lv, J., Zha, F., Tang, X., Chang, Y., Guo, X. (2021). 'Catalytic Performance of Phosphorus Incorporated HZSM-5 in Coupling Transformation of Methanol with 1-butene to Propylene', Revista de Chimie, 72(3), pp. 33-44. https://doi.org/10.37358/RC.21.3.8435

IEEE
H. Tian, Y. Nan, J. Lv, F. Zha, X. Tang, Y. Chang, X. Guo, "Catalytic Performance of Phosphorus Incorporated HZSM-5 in Coupling Transformation of Methanol with 1-butene to Propylene". Revista de Chimie, vol. 72, no. 3, pp. 33-44, 2021. [online]. https://doi.org/10.37358/RC.21.3.8435

Text
Haifeng Tian, Yongyong Nan, Jinlong Lv, Fei Zha, Xiaohua Tang, Yue Chang, Xiaojun Guo,
Catalytic Performance of Phosphorus Incorporated HZSM-5 in Coupling Transformation of Methanol with 1-butene to Propylene,
Revista de Chimie,
Volume 72, Issue 3,
2021,
Pages 33-44,
ISSN 2668-8212,
https://doi.org/10.37358/RC.21.3.8435.
(https://revistadechimie.ro/Articles.asp?ID=8435)
Keywords: The P-modified HZSM-5 zeolite; Coupling ;methanol ;1-butene; Propylene

RIS
TY - JOUR
T1 - Catalytic Performance of Phosphorus Incorporated HZSM-5 in Coupling Transformation of Methanol with 1-butene to Propylene
A1 - Tian, Haifeng
A2 - Nan, Yongyong
A3 - Lv, Jinlong
A4 - Zha, Fei
A5 - Tang, Xiaohua
A6 - Chang, Yue
A7 - Guo, Xiaojun
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2021
VL - 72
IS - 3
SP - 33
EP - 44
UR - https://doi.org/10.37358/RC.21.3.8435
KW - The P-modified HZSM-5 zeolite
KW - Coupling
KW - methanol
KW - 1-butene
KW - Propylene
ER -

BibTex
@article{RevCh2021P33,
author = {Tian Haifeng and Nan Yongyong and Lv Jinlong and Zha Fei and Tang Xiaohua and Chang Yue and Guo Xiaojun},
title = {Catalytic Performance of Phosphorus Incorporated HZSM-5 in Coupling Transformation of Methanol with 1-butene to Propylene},
journal = {Revista de Chimie},
volume = {72},
number = {3},
pages = {33-44},
year = {2021},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.21.3.8435},
url = {https://revistadechimie.ro/Articles.asp?ID=8435}
}

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