Characterization of Dimethoxybenzene Isomers and 2,2’-dihydroxy-4,4’-dimethoxybenzophenone by Voltammetry in Acetonitrile, Allyl Alcohol and Mesityl Oxide, Effect of Electrode Size

Kiss, Laszlo; Kovacs, Ferenc; Yan, Hui; Li, Heng; Kunsagi-Mate, Sandor

Laszlo Kiss, Ferenc Kovacs, Hui Yan, Heng Li, Sandor Kunsagi-Mate

Characterization of Dimethoxybenzene Isomers and 2,2’-dihydroxy-4,4’-dimethoxybenzophenone by Voltammetry in Acetonitrile, Allyl Alcohol and Mesityl Oxide, Effect of Electrode Size

Abstract:

The electrochemistry of dimethoxybenzene isomers and 2,2’-dihydroxy-4,4’-dimethoxybenzo-phenone is discussed in this paper concerning their electrooxidation in acetonitrile, allyl alcohol and mesityl oxide. The voltammograms of 1,2- and 1,4-isomers were reproducible in each solvent, only the 1,3-isomer fouled the platinum macroelectrode. In case of 2,2’-dihydroxy-4,4’-dimethoxybenzophenone a low electronically conducting film was formed in all of the investigated solvents. In mesityl oxide, the growing film showed significant adsorption capability towards the substrate molecules. Microelectrode studies shed light to interesting phenomena due to the increased mass transport to the electrode surface, in case of dimethoxybenzenes leading to more conducting polymers. The specially formed film from 2,2’-dihydroxy-4,4’-dimethoxybenzophenone demonstrated its adsorption capability towards selected compounds.

Keywords:
Keywords: dimethoxybenzenes; allyl alcohol; mesityl oxide; electropolymerization; 2;2’-dihydroxy-4;4’-dimethoxybenzophenone

Issue: 2024, Volume 75, Issue 3

Pages: 1-15

Publication date: 2024/8/6

https://doi.org/10.37358/RC.24.3.8587

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Citation Styles

Cite this article as:
KISS, L., KOVACS, F., YAN, H., LI, H., KUNSAGI-MATE, S., Characterization of Dimethoxybenzene Isomers and 2,2’-dihydroxy-4,4’-dimethoxybenzophenone by Voltammetry in Acetonitrile, Allyl Alcohol and Mesityl Oxide, Effect of Electrode Size, Rev. Chim., 75(3), 2024, 1-15.

Vancouver
Kiss L, Kovacs F, Yan H, Li H, Kunsagi-Mate S. Characterization of Dimethoxybenzene Isomers and 2,2’-dihydroxy-4,4’-dimethoxybenzophenone by Voltammetry in Acetonitrile, Allyl Alcohol and Mesityl Oxide, Effect of Electrode Size. Rev. Chim.[internet]. 2024 Mar;75(3):1-15. Available from: https://doi.org/10.37358/RC.24.3.8587

APA 6th edition
Kiss, L., Kovacs, F., Yan, H., Li, H. & Kunsagi-Mate, S. (2024). Characterization of Dimethoxybenzene Isomers and 2,2’-dihydroxy-4,4’-dimethoxybenzophenone by Voltammetry in Acetonitrile, Allyl Alcohol and Mesityl Oxide, Effect of Electrode Size. Revista de Chimie, 75(3), 1-15. https://doi.org/10.37358/RC.24.3.8587

Harvard
Kiss, L., Kovacs, F., Yan, H., Li, H., Kunsagi-Mate, S. (2024). 'Characterization of Dimethoxybenzene Isomers and 2,2’-dihydroxy-4,4’-dimethoxybenzophenone by Voltammetry in Acetonitrile, Allyl Alcohol and Mesityl Oxide, Effect of Electrode Size', Revista de Chimie, 75(3), pp. 1-15. https://doi.org/10.37358/RC.24.3.8587

IEEE
L. Kiss, F. Kovacs, H. Yan, H. Li, S. Kunsagi-Mate, "Characterization of Dimethoxybenzene Isomers and 2,2’-dihydroxy-4,4’-dimethoxybenzophenone by Voltammetry in Acetonitrile, Allyl Alcohol and Mesityl Oxide, Effect of Electrode Size". Revista de Chimie, vol. 75, no. 3, pp. 1-15, 2024. [online]. https://doi.org/10.37358/RC.24.3.8587

Text
Laszlo Kiss, Ferenc Kovacs, Hui Yan, Heng Li, Sandor Kunsagi-Mate,
Characterization of Dimethoxybenzene Isomers and 2,2’-dihydroxy-4,4’-dimethoxybenzophenone by Voltammetry in Acetonitrile, Allyl Alcohol and Mesityl Oxide, Effect of Electrode Size,
Revista de Chimie,
Volume 75, Issue 3,
2024,
Pages 1-15,
ISSN 2668-8212,
https://doi.org/10.37358/RC.24.3.8587.
(https://revistadechimie.ro/Articles.asp?ID=8587)
Keywords: Keywords: dimethoxybenzenes; allyl alcohol; mesityl oxide; electropolymerization; 2;2’-dihydroxy-4;4’-dimethoxybenzophenone

RIS
TY - JOUR
T1 - Characterization of Dimethoxybenzene Isomers and 2,2’-dihydroxy-4,4’-dimethoxybenzophenone by Voltammetry in Acetonitrile, Allyl Alcohol and Mesityl Oxide, Effect of Electrode Size
A1 - Kiss, Laszlo
A2 - Kovacs, Ferenc
A3 - Yan, Hui
A4 - Li, Heng
A5 - Kunsagi-Mate, Sandor
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2024
VL - 75
IS - 3
SP - 1
EP - 15
UR - https://doi.org/10.37358/RC.24.3.8587
KW - Keywords: dimethoxybenzenes
KW - allyl alcohol
KW - mesityl oxide
KW - electropolymerization
KW - 2
KW - 2’-dihydroxy-4
KW - 4’-dimethoxybenzophenone
ER -

BibTex
@article{RevCh2024P1,
author = {Kiss Laszlo and Kovacs Ferenc and Yan Hui and Li Heng and Kunsagi-Mate Sandor},
title = {Characterization of Dimethoxybenzene Isomers and 2,2’-dihydroxy-4,4’-dimethoxybenzophenone by Voltammetry in Acetonitrile, Allyl Alcohol and Mesityl Oxide, Effect of Electrode Size},
journal = {Revista de Chimie},
volume = {75},
number = {3},
pages = {1-15},
year = {2024},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.24.3.8587},
url = {https://revistadechimie.ro/Articles.asp?ID=8587}
}

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